Enhanced bistability by guest inclusion in Fe(II) spin crossover porous coordination polymers.

نویسندگان

  • Francisco J Muñoz Lara
  • Ana B Gaspar
  • Daniel Aravena
  • Eliseo Ruiz
  • M Carmen Muñoz
  • Masaaki Ohba
  • Ryo Ohtani
  • Susumu Kitagawa
  • José A Real
چکیده

Inclusion of thiourea guest molecules in the tridimensional spin crossover porous coordination polymers {[Fe(pyrazine)[M(CN)(4)]} (M = Pd, Pt) leads to novel clathrates exhibiting unprecedented large thermal hysteresis loops of ca. 60 K wide centered near room temperature.

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عنوان ژورنال:
  • Chemical communications

دوره 48 39  شماره 

صفحات  -

تاریخ انتشار 2012